Examples of 'allylic' in a sentence
Meaning of "allylic"
Allylic is a noun used in chemistry to refer to a group of atoms bonded to a carbon atom that is adjacent to a carbon-carbon double bond
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- Containing an allyl group, an alkene hydrocarbon group with the formula H₂C=CH-CH₂-
How to use "allylic" in a sentence
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allylic
Any suitable allylic monomers can be used.
Polarity also has an effect on allylic strain.
An allylic alcohol is also used in the process.
Solvents also have an effect on allylic strain.
The allylic alcohol is formed in a relatively short time.
Preferably it will contain an allylic or acrylic moiety.
A group attached at this site is sometimes described as allylic.
Cyclopropanating said allylic alcohol to form a carbocyclic alcohol.
The reaction product is an allylic amine.
Allylic and benzylic compounds undergo more selective oxidations.
They were also involved in the allylic substitution reaction.
Allylic and benzylic bromination.
The asymmetric catalyst reaction may be allylic substitution.
Effect of allylic strain on diastereoselectivity.
It is hypothesized to result from allylic oxidation of the enester.
See also
An allylic unsaturation imparted by allyl alcohol can also be used.
Process for preparing allylic alcohols from allylic halides.
The allylic derivative may also be added in during polymerization.
The double bond of the allylic alcohol is then reduced.
Allyl alcohol is the smallest representative of the allylic alcohols.
The carbonylation of allylic butenols or butenol esters is not disclosed.
Chirospesific synthesis of allylic amines.
Allylic double bonds.
The quinone methide intermediate reacts by abstraction of allylic hydrogen.
Methods for the oxidation of allylic alcohols are known in the art.
Other olefins include halogenated olefins such as allylic chlorides.
The allylic functionalized resin was recovered in quantitative yield as a viscous liquid.
The simplest type of molecules which exhibit allylic strain are olefins.
Few allylic alcohol copolymers have actually become commercially important.
The first one is based on a decarboxylative asymmetric allylic alkylation reaction.
Examples of allylic monomers include allyl alcohol and allyl chloride.
This reaction was also performed with the branched allylic acetate.
Compounds comprising an allylic unsaturation conferred by allyl alcohol may also be used.
Of particular interest as starting material are diols functionalized with allylic groups.
Replacing the allylic bromide with acetic anhydride leads to cyanohydrin acetates.
Copolymer resins of the invention incorporate one or more allylic monomers.
Synthesis of allylic amine cationic lipids xv is a linear process starting with aldehyde x.
An additive like morpholine was used as acceptor molecule for allylic groups.
This is because an allylic cation is a resonance hybrid of two exactly equivalent structures.
Polyether polyols made in a conventional process have predominantly allylic unsaturation.
The resulting allylic alcohol is then oxidized to the aldehyde by pyridinium chlorochromate.
Prenyltransferases are a class of enzymes that transfer allylic prenyl groups to acceptor molecules.
A propoxylated allylic alcohol can be used instead of or in addition to the allylic alcohol.
Yields are generally poor unless a symmetrical secondary allylic halide can be used.
The presence of allylic halide functionalities allows for nucleophilic alkylation reactions.
Process for the preparation of carboxylic esters defined from allylic alcohols.
The polymer may have allylic functionality within the polymer chain.
According to present invention a wide range of epoxides can be converted to allylic alcohols.
Yet another known method of allylic oxidation resorts to the use of palladium catalysts.
Even more preferred is a scaffold comprising at least two allylic halogen atoms.
