Examples of 'asymmetric hydrogenation' in a sentence
Meaning of "asymmetric hydrogenation"
A chemical process in which a molecule is hydrogenated (combined with hydrogen) in an asymmetric manner, resulting in the formation of a chiral product. This process is commonly used in organic synthesis to create compounds with specific stereochemical properties
How to use "asymmetric hydrogenation" in a sentence
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asymmetric hydrogenation
Preferably the catalysts are used in asymmetric hydrogenation.
Asymmetric hydrogenation processes are known for some compounds.
Preferably the asymmetric catalysis reaction is asymmetric hydrogenation.
Process for the asymmetric hydrogenation of carbonyl compounds obtained.
This technology provides a powerful complement to catalytic asymmetric hydrogenation.
The field of asymmetric hydrogenation continued to experience a number of notable advances.
Ruthenium catalysts and their use in the asymmetric hydrogenation of cyclopentenones.
The asymmetric hydrogenation is preferably carried out in the presence of a base.
Both processes do not involve an asymmetric hydrogenation but an addition reaction.
The asymmetric hydrogenation in this invention is carried out in an organic solvent.
Preferred is asymmetric hydrogenation.
Asymmetric hydrogenation is often an essential step in the synthesis of enantiomerically pure products.
Rhodium complex recrystallization and asymmetric hydrogenation were performed in a nitrogen filled glovebox.
The asymmetric hydrogenation is carried out in an organic solvent with or without a cosolvent.
Access to unnatural amino acid building blocks via asymmetric hydrogenation or biocatalysis.
See also
Noyori asymmetric hydrogenation.
Any chiral phosphine catalyst capable of providing asymmetric hydrogenation can be used.
In one embodiment the asymmetric hydrogenation is carried out in a hydroxylic solvent such as methanol.
It is particularly preferred that the hydrgenation conditions employed are asymmetric hydrogenation conditions.
Catalytic asymmetric hydrogenation.
The following table summarizes analyses and reaction conditions for this asymmetric hydrogenation.
Preferred bases used in the asymmetric hydrogenation are for example inorganic or organic bases.
The carbon monoxide is preferably admixed with the hydrogen used for the asymmetric hydrogenation.
Subsequent catalytic asymmetric hydrogenation would hopefully yield diastereromerically pure glycoamino acid.
The process may also be conducted to give an asymmetric hydrogenation of the alkene bond.
Asymmetric hydrogenation accounts for major part of all asymmetric synthesis on a commercial scale.
Chiral ligands are used in homogeneous catalysis, such as asymmetric hydrogenation.
Catalytic asymmetric hydrogenation involves the activation of molecular hydrogen with chiral metal complexes.
In some embodiments, the processes provided herein utilize asymmetric hydrogenation.
And asymmetric hydrogenation of imines Bakos et al.
The process as claimed in claim 26 wherein said hydrogenation is an asymmetric hydrogenation.
Asymmetric Hydrogenation of Enamine substrate a entry metal and ligand.
Being prochiral, acetophenone is also a popular test substrate for asymmetric hydrogenation experiments.
Asymmetric hydrogenation was performed in a nitrogen-filled glovebox.
Therefore, a new approach has been developed vÃa the asymmetric hydrogenation of new precursors.
Suitably, the asymmetric hydrogenation is carried out at room temperature.
An object of this invention is to provide such a process, namely an asymmetric hydrogenation process.
For example, in the asymmetric hydrogenation of statin precursors.
Moreover, the transition metal complex is useful as a catalyst for asymmetric hydrogenation.
For asymmetric hydrogenation reactions at least, such chiral phosphetanes are particularly useful.
Also, the transition metal complex is useful as a catalyst of asymmetric hydrogenation reaction.
An asymmetric hydrogenation catalyst which contains the transition metal complex of claim 4.
The present invention relates to catalysts, which are useful for asymmetric hydrogenation reactions.
As a preliminary matter, the asymmetric hydrogenation of ketones is a known transformation in organic synthesis.
The present invention concerns a process for the catalytic asymmetric hydrogenation of B-ketoesters.
Today, asymmetric hydrogenation is a routine methodology in laboratory and industrial scale organic chemistry.
As shown in Figure 13, a tranformation utilizing catalytic asymmetric hydrogenation of glycosylated amide esters was contemplated.
The asymmetric hydrogenation of step 5 can be carried out either batchwise or in a continuous manner.
Taniaphos gave excellent results in Rh - and Ru-catalyzed asymmetric hydrogenation.
The results of asymmetric hydrogenation are reported in the Table 1.
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