Examples of 'bromoacetate' in a sentence
Meaning of "bromoacetate"
bromoacetate (noun) - a type of chemical compound that contains a bromine atom and an acetate group
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- Any salt or ester of bromoacetic acid
How to use "bromoacetate" in a sentence
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bromoacetate
A few drops of pure ethyl bromoacetate are then added.
In one embodiment the alkyl haloacetate is ethyl bromoacetate.
Methyl bromoacetate is an alkylating agent.
The nitrogenated base used with ethyl bromoacetate is preferably triethylamine.
Ethyl bromoacetate ethylenediamine.
The tosylamide is then alkylated with methyl bromoacetate using a suitable base.
One mol of ethyl bromoacetate is added thereto and the whole is heated under reflux.
Treating the product of step c above with NaOMe followed by methyl bromoacetate.
The nitrogen base used with ethyl bromoacetate is preferably triethylamine.
It seems that the victim had prolonged exposure to hydrogen cyanide ethyl bromoacetate.
An appropriately substituted amine is alkylated with ethyl bromoacetate and hydrolyzed to the glycine derivative.
Their alkylation with bromoacetate and subsequent saponification can provide the corresponding carboxylic acid building blocks.
This compound can in particular be chosen from ethyl bromoacetate and ethyl acrylate.
Then, methyl bromoacetate is added at room temperature.
Esters XXX can be prepared from alkylation of hydroxybenzonitriles XXIX with methyl bromoacetate.
See also
Substance of special concern Ethyl bromoacetate Fluoride any concentration.
A process according to claim 6 wherein in step d haloacetic acid ester is ethyl bromoacetate.
Then, ethyl bromoacetate is added at room temperature.
First step 1 consisting of functionalization with an alkyl bromoacetate compound ;.
Furthermore, t-butyl bromoacetate is expensive and not easy available on the industrial scale.
Alkylation of the sodium salt of the indoles 7 with an alkyl bromoacetate gives 8.
When the addition of ethyl bromoacetate is complete, warm the reaction mixture to ambient temperature.
However, there is no optical selectivity in the reaction of an aldehyde and ethyl bromoacetate.
And ethyl bromoacetate according to the procedure described in the example 1a using NaH as a base.
The residue was dissolved in anhydrous acetonitrile, methyl bromoacetate and cesium carbonate were added.
It was confirmed from the following results that the resulting compound was tert-butyl bromoacetate.
Additional bromoacetate was added and the reaction brought to completion ( HPLC ) by refluxing overnight.
Volatile esters of bromoacetic acids, Methyl bromoacetate.
Ethyl bromoacetate any concentration Very Corrosive 2.
In one embodiment, the heterobifunctional reagent is N-succinimidyl bromoacetate.
Compound 6 Compound 4 was dissolved in DMF and ethyl bromoacetate was added together with potassium carbonate.
The process of Claim 3 wherein the alkyl haloacetate is ethyl bromoacetate.
Nitrophenols 5 were alkylated with ethyl bromoacetate derivatives to afford 6.
The free amino groups can be subsequently reacted with N-hydroxysuccinimidyl bromoacetate.
After stirring for 20 min ethyl bromoacetate is added dropwise.
For example ; the starting carboxylate for the compound of Example 4 is methyl bromoacetate.
An additional 86 µL of ethyl bromoacetate were added and the reaction stirred an additional 24 h.
General procedure II, Alkylation of phenols with ethyl bromoacetate.
Alkyation with ethyl bromoacetate followed by cyclisation with potassium tert - butoxide gives ( 5 ).
Starting with hydroxybenzonitriles XXIX, alkylation with methyl bromoacetate gives esters XXX.
MDMA ( 1 ) is reacted with methyl bromoacetate in the presence of a base to give compound 7.
A method in accordance with claim 5, wherein said alpha-haloester is ethyl bromoacetate.
The solution was stirred 10 min then ethyl bromoacetate was added all at once.
The first step consists of an O-alkylation of the 3-bromophenol by methyl bromoacetate.
This material is alkylated with tert-butyl bromoacetate under phase transfer conditions resulting in ether 91.
Preferably the compound of formula ( IV ) is ethyl bromoacetate.
Both compounds are then alkylated with tert-butyl bromoacetate under phase transfer conditions providing 64 and 68.
The NMR spectrum was consistent with the major product being bromoacetate 18.
Using t - butyl bromoacetate instead of methyl bromoacetate did not improve the yield ( Scheme 3 ).
Suitable alkylating agents include bromoacetonitrile, ethyl 4-chloroacetoacetate, methyl bromoacetate and chloroethylamine hydrochloride.
