Examples of 'coordination sphere' in a sentence
Meaning of "coordination sphere"
The coordination sphere in chemistry refers to the central metal atom/ion and the ligands surrounding it in a complex. It plays a crucial role in determining the geometry, structure, and properties of the complex
How to use "coordination sphere" in a sentence
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coordination sphere
All feature titanium in an octahedral coordination sphere.
The coordination sphere is completed by two water molecules.
It occupies one position in the coordination sphere.
The coordination sphere of the zinc ion is approximately tetrahedral.
The latter are said to reside in the second coordination sphere.
Second coordination sphere.
Supramolecular supports may reproduce a number of second coordination sphere effects.
The coordination sphere of the cationic complex is completed by solvation with a nitromethane molecule.
Only the water molecules of the second coordination sphere are influenced.
The first coordination sphere refers to the molecules that are attached directly to the metal.
Molecules that are attached noncovalently to the ligands are called the coordination sphere.
Water molecules are not necessary to complete the coordination sphere of the triethylenetetramine molecule.
The ligand loss or gain is associated with a geometric change in the complexes coordination sphere.
The presence of the ligand inside of the metal coordination sphere affects the metal reactivity.
They are commonly found as counterions for cationic metal complexes with an unsaturated coordination sphere.
See also
The other two ligands in the Tc coordination sphere are tricine and a phosphine.
Rearrangements where the relative stereochemistry of the ligand change within the coordination sphere.
The metal and its coordination sphere are near 1 nanometer in size.
Additional complexing agents may be added to complete the coordination sphere of the metal.
The geometry of the Ti coordination sphere in these complexes is best described as pseudo-tetrahedral.
The central metal ion or atom and the ligands are collectively called the coordination sphere.
FIGURE 14 shows a coordination sphere for ( I ) triethylenetetramine and ( II ) triethylenetetramine disuccinate.
Crown-ethers bind to polyamine complexes through their second coordination sphere.
These are Coordination entity, Ligands, Coordination number, Coordination sphere and Coordination polyhedron.
The central atom or ion, together with all ligands comprise the coordination sphere.
The atom of phosphorus is held in the coordination sphere of tungsten ( W ( CO ) 5 ).
The UCl3 motif features 9-coordinate metal with a tricapped trigonal prismatic coordination sphere.
Moreover, the ligand preferably places a restriction on the coordination sphere of the metal.
One of the terminal Li centers is pseudo-tetrahedral in an N4 coordination sphere.
Thus it can attack from both inside and outside the coordination sphere of Pd ( II ).
The salt Sr2Zn(OH)6 features zinc in an octahedral coordination sphere.
Macrocyclic molecules such as cyclodextrins act often as the second coordination sphere for metal complexes . [ 6 ] [ 7 ].
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