Examples of 'dess-martin' in a sentence
Meaning of "dess-martin"
Dess-Martin is an adjective used in organic chemistry to describe a specific oxidation reagent known as the Dess-Martin periodinane
How to use "dess-martin" in a sentence
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dess-martin
The use of Dess-Martin periodinane is preferred.
An example of suitable oxidizing agent is Dess-Martin periodinane.
The Dess-Martin periodinane is a mild oxidant for the conversion of alcohols to aldehydes or ketones.
A preferred oxidising agent is the Dess-Martin periodinane.
Dess-Martin periodinane is mainly used as an oxidant for complex, sensitive and multifunctional alcohols.
The oxidizing agent includes a Dess-Martin reagent, which is a iodobenzene derivative.
The resulting alcohol is oxidized to the corresponding ketone using the Dess-Martin periodinane.
The alcohol then undergoes the Dess-Martin reaction for conversion to a ketone.
Suitable oxidation conditions include the Swern reaction and the use of the Dess-Martin periodinane reagent.
Preferred oxidation reactions are the Dess-Martin oxidation, PDC oxidation or Swern oxidation in dichloromethane.
In some embodiments, the stoichiometric oxidant is Dess-Martin periodinane.
Using the Dess-Martin reactant.
Such preparation may, for example, be effected by the procedure known as Dess-Martin oxidation.
Examples of first oxidizing agent are Dess-Martin periodinane and N-ethyl maleimide.
More preferably, the process comprises treating a compound of formula ( II ) with Dess-Martin periodinane.
See also
Subsequent oxidation, for example through reaction with Dess-Martin periodinane, provides the corresponding aldehyde VII.
Then, Dess-Martin periodinane was added.
These oxidations are preferably carried out with Dess-Martin periodinane in chloroform at reflux.
A second batch of Dess-Martin periodinane ( 755 mg ) was added and the reaction was stirred overnight.
Generally, a preferred oxidant is Dess-Martin periodinane.
An additional 40 mg of Dess-Martin periodinane was added to drive the reaction to completion.
The primary alcohol 18 was oxidized to give aldehyde 19 using Dess-Martin periodinane.
Finally, oxidation with Dess-Martin reagent yielded the desired a-ketoamides.
The method of claim 12, wherein the oxidizing agent of step i comprises MnO2 or Dess-Martin periodinane.
Both N-Fmoc-aminoaldehydes were obtained vía standard Dess-Martin oxidation of the corresponding N-Fmoc aminoalcohol.
Subsequent Dess-Martin oxidation of the alcohol generated the target aldehyde, Compound 130.
Removal of the trimethylsilyl protecting group and Dess-Martin oxidation afforded the triene 35.
Oxidation of 40 with Dess-Martin reagent and removal of the silyl protecting group gives ± acylfulvene analog 42.
Of these, m-chloroperbenzoic acid, Oxone ( registered trademark ), Dess-Martin periodinane are preferable.
To the solution is added Dess-Martin periodinane at 0 °C, and resulting solution is stirred.
The alcohol ( XXXI ) may be converted to the corresponding aldehyde ( XXXIII ) vía Dess-Martin Oxidation.
The resulting solution was treated with Dess-Martin periodinane and stirred at room temperature for 30min.
Non-limiting examples of the oxidizing agent may include Dess-Martin periodinane, hydrogen peroxide, or oxalyl chloride.
Swem oxidation, Dess-Martin oxidation, CrVI oxidations, etc.
Upon oxidation of crude Compound 8 with the Dess-Martin periodinane Dess et al ., J. Org.
Oxidation for example with MnO2 or Dess-Martin periodinane provides diarylketones lvii ( Method AF ).
Hypervalent iodine compounds, such as Dess-Martin periodinane or 2-Iodoxybenzoic acid.
For example, 8.5 may be treated with Dess-Martin periodinane in a solvent such as dichloromethane.
The latter was oxidised with Dess-Martin reagent to the required 2-aryl-cyclohexanone.
This diol 3b is selectively oxidized with Dess-Martin reagent to give C-3 keto derivative 3c.
