Examples of 'diazomethane' in a sentence
Meaning of "diazomethane"
Diazomethane is a chemical compound used in organic chemistry for various synthetic purposes
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- the simplest diazo compound, CH₂=N⁺=N⁻; a toxic, yellow, explosive gas; used in analytical chemistry to convert carboxylic acids into their methyl esters for analysis via gas-liquid chromatography
How to use "diazomethane" in a sentence
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diazomethane
Diazomethane is also frequently used as a carbene source.
The simplest example of a diazo compound is diazomethane.
Deaths from diazomethane poisoning have been reported.
The product was reacted with diazomethane in ether.
Excessive diazomethane was decomposed with acetic acid.
Analytes derivatised to methyl esters by diazomethane.
A solution of diazomethane in ether is added up to maintenance of a yellow colour.
The solvent is removed in vacuo to provide diphenyl diazomethane.
The excess of diazomethane is controlled by means of acetic acid.
The organic layer that contains diazomethane was separated.
A diazomethane solution was cooled in an ice bath.
An excess solution of diazomethane in ether was added.
The diazomethane is generated in a reactor vessel of basic design.
The residue was then methylated by treatment with diazomethane.
Of diazomethane was added until the reaction was done.
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To generate an alkylidene carbene a ketone can be exposed to trimethylsilyl diazomethane.
The excess diazomethane was removed using a stream of nitrogen.
Creating a new kind of diazomethane.
Diazomethane was added in portions until the reaction was complete.
To the mixture was added excess amount of an ethereal solution of diazomethane.
Excess diazomethane in ether was then added.
The filtrate was partially concentrated and was treated with diazomethane.
Diazomethane is carcinogenic and explosive.
To this mixture was slowly added an excess solution of diazomethane in ether.
The excess diazomethane was destroyed by a few drops of acetic acid.
A few drops of acetic acid were added to remove diazomethane excess.
The excess diazomethane is then expelled under a stream of nitrogen.
The electronic and vibrational structures of the diazomethane molecule were studied.
Excess diazomethane in ether was then added to the stirred solution.
It is a less explosive alternative to diazomethane for the methylation of carboxylic acids.
Excess diazomethane was removed by addition of a few drops of acetic acid.
This is evaporated down to get rid of excess methanol and diazomethane.
The residual diazomethane was destroyed by the addition of aqueous HCl.
The resulting organic phase is continuously fed to the diazomethane stages.
The excess diazomethane was then quenched with acetic acid.
The esterification of carboxylic acid may be achieved by diazomethane in a usual manner.
Excess diazomethane was quenched with AcOH and solvent evaporated.
The method therefore does not avoid the handling of a precursor of diazomethane.
Diazomethane laboratory preparation.
It was then treated with diazomethane to afford the corresponding methyl esters.
Pyrazoles can be readily synthesized by the reaction of diazomethane with acetylene.
The diazomethane is toxic and explosive so the reaction has to be controlled.
Describe a microreactor for the mixing of a diazomethane precursor and a base.
The excess diazomethane is destroyed by adding one drop of acetic acid.
To this was added an etherial solution of diazomethane until the yellow color persisted.
The diazomethane is a very reactive source of methyl after deprotonation of the acid.
You observe releasing nitrogen by adding diazomethane to the methyl styrene intermediate.
The diazomethane reactant is preferably used in this reaction without isolation or purification.
The ether extract was treated with an excess of diazomethane and then concentrated.
The excess diazomethane was removed vía argon bubbling and the solvent was stripped.
