Examples of 'nucleophilic displacement' in a sentence
Meaning of "nucleophilic displacement"
nucleophilic displacement: A chemical reaction in which a nucleophile displaces another group in a molecule. This process is common in organic chemistry and involves the substitution of an atom or group by a nucleophile, resulting in the formation of a new chemical compound
How to use "nucleophilic displacement" in a sentence
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nucleophilic displacement
Followed by nucleophilic displacement with azide.
Cyclen compounds can be synthesized by combining two separate parts by nucleophilic displacement.
The conditions appropriate for such nucleophilic displacement reactions are detailed below.
These grafts were then attached to mesylated or tosylated cellulose triacetate by nucleophilic displacement.
The acylation step is then followed by nucleophilic displacement with a primary amine.
This method exploits the facility with which an aromatic nitro group can undergo nucleophilic displacement.
The sulfide can be prepared vía a nucleophilic displacement reaction of the ortho fluoride.
The group LG is herein defined as a leaving group subject to nucleophilic displacement.
The enolate reacts by nucleophilic displacement at the electron deficient oxygen of the oxaziridine ring.
Similar considerations apply when considering the nucleophilic displacement reaction separately.
The nucleophilic displacement and Suzuki coupling reactions are analogous to those described above.
The reactivity of carbonyl and aromatic compounds for the nucleophilic displacement is investigated theoretically.
The nucleophilic displacement reaction is shown below,.
LG is a leaving group for nucleophilic displacement by thio.
Nucleophilic displacement of the chlorine atom with ethylamine resulted in the formation of compound 5.
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The foregoing oxidation and nucleophilic displacement reactions are illustrated in Scheme VI.
Nucleophilic displacement of bromide compound 58 in DMF occurred with no indication of Michael addition products.
In a related reaction, alkyl halides undergo nucleophilic displacement by phenoxides.
The nucleophilic displacement inverts the center, thus converting the glucopyranose into a mannopyranose.
Similar considerations apply when considering the nucleophilic displacement reaction ( s ) separately.
Under the nucleophilic displacement conditions, a strong base may be added to facilitate the transformation.
Alternatively, Ra can be removed by nucleophilic displacement using NaI.
Nucleophilic displacement with a thiocarboxylic acid Org . Syn.
A general procedure for amine nucleophilic displacement of an alkyl mesylate is shown below,.
The sources of the starting materials for these reactions are described subsequently . Nucleophilic Displacement.
Phosphorus halides undergo Nucleophilic displacement by organometallic reagents such as Grignard reagents.
Typical procedure for chloroacetylation of a compound of formula I wherein R1 is hydrogen followed by nucleophilic displacement.
The second step involves nucleophilic displacement of the chloride in ( XVa ) by cyanide.
The chloro is then replaced with a protected sulfur or a protected disulfide, e.g. vía nucleophilic displacement.
Typical solvents for the nucleophilic displacement include, but are not limited to, alcohols.
They are compatible with the reaction conditions of acylation ( acetylation, benzoylation, tosylation ) and nucleophilic displacement.
General Procedure B, Nucleophilic displacement of an aryl halide with an amine.
This represents the first example of preferential external nucleophilic displacement at C-2 ´ vs.
Reductive alkylation or nucleophilic displacement of iodine gives chloride 11.
Nucleophilic displacement of chloride 11 with the appropriate amine affords the secondary amine 13.
Alternatively R9 was elaborated after the coupling reaction by nucleophilic displacement of a mesylate shown below,.
Keywords, nucleophilic displacement at phosphorus, alkali-metal-ion catalysis.
The 2-fluorophenol compound 4 is coupled with compound 3 by nucleophilic displacement.
Nucleophilic displacement of bromide 17 with the appropriate amine affords amine 18.
The nitrile 4 ( a ) is prepared by a nucleophilic displacement of the chloride compound ( 3a ) with cyanide.
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