Examples of 'rearrangement reaction' in a sentence
Meaning of "rearrangement reaction"
rearrangement reaction: A chemical reaction in which the arrangement of atoms in molecules is altered to form new compounds or products
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- any of many classes of reaction in which an atom or bond moves or migrates from a site in a reactant molecule to a different site in a product molecule
How to use "rearrangement reaction" in a sentence
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rearrangement reaction
The rearrangement reaction is a thermodynamically controlled reaction.
There will be described aspects of a rearrangement reaction.
The rearrangement reaction is preferably a known rearrangement reaction.
When the isomerization occurs intramolecularly it is considered a rearrangement reaction.
The rearrangement reaction is carried out in the presence of the solvent.
The added methanesulfonic acid facilitates the subsequent rearrangement reaction.
This rearrangement reaction proceeds via enolate formation followed by acyl transfer.
He is best known for the McLafferty rearrangement reaction that was observed with mass spectrometry.
The rearrangement reaction is proceeded in the presence of a cyanide and a mild base.
This is because propylene oxide readily undergoes a rearrangement reaction in the presence of strong bases.
The rearrangement reaction of the invention may be carried out in an inert solvent.
A too small amount of thionyl chloride is undesirable because the rearrangement reaction does not proceed.
The name of the rearrangement reaction comes from the rearrangement of pinacol to pinacolone.
Apparatuses used in a Beckmann rearrangement reaction.
The rearrangement reaction takes place by reacting the nitrosamine precursor with hydrochloric acid.
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The Smiles rearrangement is an organic reaction and a rearrangement reaction.
The solvent used in the rearrangement reaction is a polar solvent for example a nitrile solvent.
A too small amount of a Beckmann rearrangement catalyst is undesirable because a Beckmann rearrangement reaction ceases.
Rearrangement reaction solution transferred to the catalyst removal step is washed with water under heating.
This seems that the catalyst accelerates the formation of diaziridinone derivative or Hoffmann rearrangement reaction.
The Claisen rearrangement reaction is conducted by heating in a suitable solvent.
The comprehensive general view of the Curtius rearrangement reaction is found in Chem.
Beckmann rearrangement reaction There will be described a Beckmann rearrangement reaction.
The amine XXIV can be prepared by the Hofmann rearrangement reaction of XXIII.
A rearrangement reaction of the carbocation follows with ring closure to 9.
The Criegee rearrangement is a rearrangement reaction named after Rudolf Criegee.
This is the general form of the Baker-Venkataraman rearrangement reaction.
Consequently, this rearrangement reaction must be minimized.
A process for producing a polyamine comprising a rearrangement reaction step of,.
In the next rearrangement reaction nitrogen is expulsed and a proton transferred to 6.
The amine XXIX can be prepared by the Hofmann rearrangement reaction of XXVIII.
Thus, by this rearrangement reaction there is an alternative preparation method for the active compounds.
In a second step, the epoxydodecane is subjected to a rearrangement reaction resulting in cyclododecanone.
This rearrangement reaction is carried out at a temperature of about zero to about 50 degrees C.
Furthermore, a larger post-heating apparatus is required for completing the rearrangement reaction.
The second step is a hydrochloric acid-catalyzed rearrangement reaction and ring-closing reaction to tetrahydrocarbazole.
A Beckmann rearrangement reaction can be conducted under reduced pressure, ambient pressure or increased pressure.
Presently preferred media for the above-described rearrangement reaction is 19 % aqueous hydrochloric acid.
Figure 1. Amadori rearrangement reaction of D-glucose with N-terminal Val residue of hemoglobin in vivo.
Compound ( VIIIb ) is produced by the Claisen rearrangement reaction of compound ( VIIb ).
The Lewis acid promotes the rearrangement reaction and minimizes epimerization at the alpha-carbon atom.
Treatment of this hydrazine with mineral acids induces a rearrangement reaction to 4,4'-benzidine.
The Wagner-Meerwein rearrangement reaction is named after Wagner and Hans Meerwein.
On the other hand, the Claisen rearrangement reaction itself is a known reaction.
Occurrence of the rearrangement reaction will result in producing the compound ( 2 ).
Step ( i ), This reaction is a rearrangement reaction using a catalyst.
In the present invention, the Claisen rearrangement reaction is induced in the compound ( 2 ).
In particular the present invention relates to a rearrangement reaction of N-7 alkylated to N-9 alkylated purine derivatives.
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Examples of using Rearrangement
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Rearrangement of the requirements on the certificate of approval
Pericyclic reactions are usually rearrangement or addition reactions
The rearrangement is widely used in organic synthesis