Examples of 'solvolysis' in a sentence
Meaning of "solvolysis"
solvolysis (noun): A chemical reaction in which a bond is broken with the help of a solvent
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- Any reaction, between a solute and its solvent, in which one or more bonds of the solute are broken; specifically a substitution, elimination or fragmentation reaction in which the solvent is the nucleophile.
How to use "solvolysis" in a sentence
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solvolysis
Solvolysis involving water is called hydrolysis.
The ion pair concept explains stereochemistry in solvolysis.
Solvolysis of the cyclopropyl tosylates is discussed.
The reactor is also heated to the solvolysis temperature.
The solvolysis may be conducted at room temperature or higher.
The inhibitor can resist solvolysis up to one to three hours.
Therefore nanostructural changes have occurred due to solvolysis process.
The tetraalkyl tins do not undergo solvolysis readily or possess catalytic activity.
Electron donating substituents dramatically increase the rate of solvolysis.
The solvolysis can also be a hydrolysis carried out by using the above bases.
Catalytic pyrolysis and solvolysis.
Additional specific rates of solvolysis have been determined for acetyl chloride and diphenylacetyl chloride.
The temperature dependence of kinetic isotope effects in solvolysis is also investigated.
The solvolysis can also be a hydrolysis using for example the bases mentioned above.
The large amount of sugar greatly reduces solvolysis of the inhibitor.
See also
Benzyl derivatives undergo solvolysis at rates that are well described by the Hammett equation.
This generally occurs in highly polar solvents through a process called solvolysis.
The protic solvent employed for the solvolysis to occur is ethanol and most preferably methanol.
Researchers adapted the physicochemical separation and recovery process called solvolysis.
With alcohols, partial solvolysis may occur.
Neutral nucleophilic reactions with solvents such as alcohols and water are named solvolysis.
A lack of solvolysis and racemization ; and.
One functional group which is particularly prone to hydrolysis or solvolysis is a carboxylic ester.
Solvolysis of the brominated derivative, and.
These groups are strongly electron donating and enormously accelerate the rate of spontaneous solvolysis.
Typically, the hydrolysis or solvolysis will be acid hydrolysis.
Subsequently the glycosidic linkages of the resulting galactose residues are cleaved selectively by HF solvolysis.
Schleyer also identified solvolysis mechanisms, including reactive intermediates.
Its intermediacy is implicated in the solvolysis of 1.
Other exo-halides underwent solvolysis via aziridinium ion intermediates.
Preferably, azeotropic distillation is performed to drive the solvolysis to completion.
Many reactions studied are solvolysis reactions where a solvent molecule - often an alcohol, is the nucleophile.
Trialkylsilyl blocking groups may be removed for example by solvolysis e.g. by alcoholysis.
Secondly, a partial effect of, solvolysis of the biomass is observed, facilitating the subsequent hydroconversion reactions.
The flavorant is released upon pyrolysis, heating, or solvolysis of the tobacco or food product.
As the method for solvolysis, a generally used solvolysis method for enols can be used.
The C-D ester bond is also sensitive to solvolysis.
A new treatment of the solvent effect on the solvolysis of tert-butyl chloride is proposed.
Preferably, the solvolysis reaction is carried out at a temperature comprised between room temperature and reflux.
Said acyl radicals may be removed by hydrolysis, solvolysis or reduction depending on their nature.
This order is the reverse of that observed for SN1 solvolysis.
They do not elicit solvolysis phenomena and most stabilise short-lived reactive intermediates.
A process in accordance with Claim 1 wherein said solvolysis promoter is acetic acid.
The solvolysis profile is shown below,.
This is one of the lowest m values for a reaction that is unambiguously an SN1 solvolysis.
Followed by a step of solvolysis of the compound of formula ( 2 ) obtained.
FIG . 3 shows what remains of the composite material at the end of the solvolysis.
Absence of solvolysis and racemization ;.
Process according to claim 1 or 2, wherein said cleavage is performed by solvolysis.
Under such conditions, the solvolysis is completed in about 10 hours.
