Examples of 'stereoselectivity' in a sentence
Meaning of "stereoselectivity"
stereoselectivity (noun) - This phrase refers to the phenomenon in chemistry where a reaction selectively produces a particular stereoisomer (spatial arrangement of atoms) over others. It describes the preference of a reaction for one stereoisomeric product
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- The condition of being stereoselective or a measure of the extent to which a reaction is stereoselective
How to use "stereoselectivity" in a sentence
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stereoselectivity
Stereoselectivity is important to reduce the cardiotoxicity of bupivacaine.
Factors that affect the stereoselectivity are proposed.
This stereoselectivity is explained in the scheme below.
Sigmatropic rearrangements can offer high stereoselectivity.
The reactivity and stereoselectivity of this addition is discussed.
The reduction does not occur with complete stereoselectivity.
Exclusive trans stereoselectivity is observed for cyclic epoxide.
Bidentate phosphine ligands are common in asymmetric reactions to enhance stereoselectivity.
The pharmacological profile is determined by stereoselectivity of pharmacodynamics and pharmacokinetics.
Other substrates reacted with generally good to poor stereoselectivity.
Evidence exists for stereoselectivity in hepatic metabolism of numerous drugs.
The diethyl enol phosphate gave the highest stereoselectivity.
The stereoselectivity is influenced by the substitution pattern of the diene in some cases.
A number of examples of interesting stereoselectivity were encountered.
Catalyst productivity at standard conditions exhibits an inverse relationship with stereoselectivity.
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No obvious effect of solvents on chlorination or stereoselectivity of final products was observed.
The stereoselectivity of these additional sites was demonstrated by using two groups of stereoisomers.
This increased rigidity influences the stereoselectivity of the polymerization process.
The stereoselectivity of the reaction is discussed and compared with experimental results.
Attempts have been made to improve the stereoselectivity and yield of key steps.
The stereoselectivity of the hydrogenation can be controlled by appropriate choive of the catalyst.
A few very specific types of metallocenes have been found to have isotactic stereoselectivity.
This can also be stated as high stereoselectivity or high selectivity ratio in the reaction.
In conclusion the above disclosed cyclovitamin route of synthesis provides good stereoselectivity.
This type of substituents also provides excellent stereoselectivity in the fluorination reaction.
Stereoselectivity is obtained where the catalyst complex comprises one or more asymmetrical ligands.
Efforts continue to develop asymmetric reactions with the highest possible stereoselectivity.
The reduction takes place with high stereoselectivity to give the desired amine isomer.
Stereoisomers are interesting substrates in glucuronidation studies since some UGTs display stereoselectivity.
The reaction temperature influences the stereoselectivity and rate of reaction in the hydrolysis reaction.
Such a result is very inferior to the present conversion where a high stereoselectivity is achieved.
Catalyst system for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins.
The reaction solvent used plays a critical role in the stereoselectivity of glycosylation.
In an earlier work complete stereoselectivity for this transformation has been reported M.
The cosolvent used has the effect of considerably improving the hydrolysis stereoselectivity.
Vedejs has put forth a theory to explain the stereoselectivity of stabilized and unstabilized Wittig reactions.
The stereoselectivity of the reaction was studied on menthyl fumarate,.
The addition of HMPA is known to reverse the stereoselectivity of deprotonation.
Interestingly, the stereoselectivity varied dramatically with reaction temperature.
The two classes of Msrs conversely present an opposite stereoselectivity towards the sulfoxide function.
However, stereoselectivity is not high enough for preparative synthesis.
Quantitative determination of the stereoselectivity of SL perception.
These enzyme-based conjugations have the advantages of regioselectivity and stereoselectivity.
Regioselectivity and stereoselectivity of the Dies Alder reactions.
An aldol condensation of 8c shows little stereoselectivity.
Regio and Stereoselectivity.
Enzyme-based syntheses have the advantages of regioselectivity and stereoselectivity.
When the stereoisomers are enantiomers, the stereoselectivity is referred to as enantioselectivity.
In addition, resolution processes using these agents provide poor stereoselectivity.
A co-catalyst may also improve the stereoselectivity or regioselectivity of a polymerization reaction.
