Examples of 'steric hindrance' in a sentence
Meaning of "steric hindrance"
steric hindrance: This phrase is a term used in chemistry to describe the prevention of a reaction due to the spatial arrangement of atoms in molecules
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- Any of several effects, most common in organic chemistry, in which the structure or reactivity of a molecule is affected by the physical size and proximity of neighbouring parts of the molecule.
How to use "steric hindrance" in a sentence
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steric hindrance
Steric hindrance is a key factor in this reaction.
Preferred is methoxy having small steric hindrance.
Steric hindrance probably prevents further trimming.
A monomeric configuration may decrease steric hindrance.
Steric hindrance is a consequence of steric effects.
Preferred is acetoxy having small steric hindrance.
Steric hindrance forbids the existence of rubidium or caesium nitride.
The reaction is subject to steric hindrance by ortho substituents.
They prevent their agglomeration by acting on steric hindrance.
The confirm the small steric hindrance contribution seen on the hE.
The diaxial isomer is disfavored due to steric hindrance.
The influence in steric hindrance of the monomers affected their reactivity.
The regioselectivity can also be effected by steric hindrance.
Due to steric hindrance.
Chemical modification contributes resistance to retrogradaiton vía steric hindrance.
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This provides a good deal of steric hindrance to hydrolysis.
Another method of avoiding deleterious anion degradation is by steric hindrance.
Steric conjugates are used in steric hindrance methods for homogeneous assay.
They prevent their agglomeration by taking advantage of steric hindrance.
Steric hindrance can also be used to prevent cutting at the gaps.
This is presumed to be a steric hindrance effect.
By steric hindrance.
One explanation of this competitive binding competition is steric hindrance.
Steric hindrance is minimized by the action of a spacer arm constituent of the chelate.
These are suitably basic and do not offer a steric hindrance.
Steric hindrance between adjacent groups can also affect torsional bond angles.
This provides a favorable microenvironment without complications due to steric hindrance.
This inhibition can be due to steric hindrance or modification which prevents ligand binding.
Tributyltin azide in relatively high yields for reasons of steric hindrance.
This proximity leads to a significant steric hindrance which strongly hinders coupling to target molecules.
The reaction of epimeric esters can be severely slowed by steric hindrance of solvation.
This steric hindrance is believed to provide the phenolic compounds with its stabilizing properties.
A cis molecule tautomerizes to become trans and decrease the steric hindrance.
Any chiral alcohol having no excessive steric hindrance can be used in the present method.
Trials of regioselectivity control were made by using groups with enhanced steric hindrance.
The steric hindrance has been found to occur with molecules having a highly substituted central atom.
Neutralisation of the ortho isomer is much more difficult because of steric hindrance.
The materials prevent adhesion vía steric hindrance and inhibit direct contact between adjacent tissues.
Modification of the crystal habit removes some of the problems of steric hindrance.
This provides for less steric hindrance and provides great strength for the structure.
Often the reasons for the retardation can be traced to steric hindrance.
Steric hindrance would prevent the alcohol from accessing the iminium of IFO.
The most apparent attribute of the bridge is its effect on steric hindrance.
Such dissociation alleviates a strong steric hindrance which allows repair complexes access to the damaged DNA.
The most apparent feature of the bridge is its effect on steric hindrance.
Steric hindrance is often exploited to control selectivity, such as slowing unwanted side-reactions.
Reaction at a particular site may be restricted or prevented by steric hindrance or suitable protection.
If the steric hindrance is too great, they will weaken the stability of the hybridization.
It is known that most drugs have positions that are not sensitive to steric hindrance.
There are also examples of non-covalent steric hindrance including many repressor molecules.
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Examples of using Hindrance
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Marriage is a hindrance in carrying out our missions
Later there was more of a sense of hindrance or delay
He was a real hindrance to the band in many ways
Examples of using Steric
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Steric factor ρ is a term used in collision theory
Molecular weight measured by steric exclusion chromatography
The steric effect makes reactions difficult
