Examples of 'thiolate' in a sentence
Meaning of "thiolate"
Thiolate means to treat or react with a thiol compound, typically used in chemical reactions or processes
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- any derivative of a thiol in which a metal atom replaces the hydrogen attached to sulfur RSH => RS⁻M⁺
How to use "thiolate" in a sentence
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thiolate
The thiolate can be in the form of a salt.
The conjugate base of a thiol is called a thiolate.
Metal thiolate functionality is pervasive in metalloenzymes.
The product obtained is itself condensed with a thiolate.
The resulting thiolate salt is a useful demethylating reagent.
It is a red volatile solid that is classified as a transition metal thiolate complex.
The thiolate anion can be prepared separately or in situ.
It will be appreciated that the above structure merely represents an idealized representation of thiolate.
The thiolate of a mercaptan is prepared with one equivalent of a base.
It can be seen that the gold compound is not the present gold thiolate.
The nucleophile is a thiolate ion rather than a hydroxyl group.
A thiolate is a derivative of a thiol in which a metal atom replaces the hydrogen bonded to sulfur.
The reaction involves nucleophilic attack of the thiolate ion resulting in a displacement of the halide.
Thiolate also works for the benzthiazolesulfonamides and the alkyl substituted anthracenesulfonamides.
The nucleophile can be a thiol or thiolate anion prepared from an aryl thiol discussed below.
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The thiolate salt was prepared from ethanethiol and sodium hydride under standard conditions.
Compound II is a thiol or the corresponding thiolate.
A series of heteroleptic thiolate bismuth complexes have been isolated and characterized.
HSA contains one native thiolate group.
The fifth ligand is a thiolate anion from a cysteinyl residue of the polypeptide.
Example I Coating of a titanium implant with octadecyl thiolate.
Thiolate groups in reduced peptides are highly reactive and can interact to reform disulfide bonds.
The mesylate so obtained is substituted by the thiolate derivative of IX to afford XIX.
Consequently, thiolate ligand often bridge pairs of metals.
The mesylate so obtained is substituted by the thiolate derivative of IX to afford XVI.
Then the thiolate is added to the oxetanone solution over 3 minutes.
The Hcy thiolate.
Instead of using the thiol, it is possible to use the corresponding thiolate.
Upon enzyme hydrolysis, the thiolate is released as a product.
In this basic environment, this thiol could become a thiolate ion.
Typically, organomercury thiolate compounds are prepared from organomercury chlorides.
The oxygen-sulfur exchange reaction is carried out using an alkyl thiolate.
A suitable mixture of thiophenol, thiolate and a base may also be used.
These thiolates are preferably alkaline salts, particularly sodium or potassium thiolate.
Process of cross-linking a halogenated polymer by means of a coupling agent based on thiolate.
Use of a pre-formed thiolate can allow maintenance of a protecting group.
Represents a leaving group, which can be easily displaced by metal thiolate in nucleophilic substitution reaction.
Typically, the thiolate is generated in situ and is used without further purification.
Reacting the iodosulfonamide formed in step ( c ) under suitable conditions with a thiolate to form the mercaptotrisaccharide.
In the presence of a base, a thiolate anion is formed which is a very powerful nucleophile.
The secondary amino group in N-methylpiperazine or a thiolate group.
The thiolate can advantageously be prepared in situ in accordance with the reaction scheme,.
Preparation of the sodium thiolate of N-ethylthioglycolamide.
Where the thiolate is a salt, it can be made for instance by reaction with a base.
The thiol group can be deprotonated by base to derivate a neutral iron ( II ) thiolate complex.
The novel PyOX-derived thiolate was used to form a novel chiral gold nanoligand.
Saponification of imidate 5 and formation of sodium thiolate 6.
Once thiolate addition occurs, elimination of the remaining sulphinic acid moiety becomes possible.
Suitable bases to generate the thiolate include Hünigs base and potassium t - butoxide.
It can be seen that the composition contains 10 % gold as the thiolate.
