Examples of 'ylide' in a sentence
Meaning of "ylide"
ylide (noun) - In chemistry, ylide refers to a neutral molecule with opposite charges on two atoms
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- Any organic compound in which two adjacent atoms are connected by both a covalent and an ionic bond; normally written X⁺–Y⁻
How to use "ylide" in a sentence
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ylide
The three ylide classes.
This ylide especially has the advantage of being easy to prepare.
Last is the intramolecular azomethine ylide reaction with alkene.
An equivalent of a strong base is added slowly to produce the ylide.
Said ylide are generally prepared by treatment of a phosphonium salt with a base.
The reaction employs a phosphazene base to promote formation of the ylide.
Stability of the ylide with higher stability similarly leading to greater reversibility.
Triphenylphosphine then attacks the nascent carbene to form the reactive ylide.
Reacting the phosphorus ylide with the aldehyde substrate yields a dibromoolefin.
A ketene intermediate has been postulated in the catalytic carbonylation of the iodonium ylide.
Fragmentation of the carbonyl ylide is the dominant process in the solution thermolysis of methoxyoxadiazoline.
The reaction was warmed to room temperature to give a deep red ylide solution.
Our work here is focused on the chiral sulfur ylide mediated asymmetric imine aziridinations.
Preferably the ylide is prepared in situ prior to addition of a compound of formula VI.
Cyclopropyl aldehydes or ketones are added dropwise to the ylide and stirred at room temperature.
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This ylide undergoes a Wittig Reaction when exposed to an aldehyde.
Another synthetic method comprises reaction of a phosphorus ylide derived from benzodithiole with an acridone compound.
The ylide compound is prepared by proceeding via a diazonium intermediate, to which is added a base.
Step A involves the intramolecular insertion ofNH using a ketosulfoxonium ylide to form a cyclic product.
For instance an azomethine ylide is a dipole in the Prato reaction with fullerenes.
One approach to the styrene oxide is the reaction of 3-chlorobenzaldehyde with trimethylsulfonium ylide.
Onium Ylide chemistry.
Thereby, the aminoalkyl epoxides are prepared by reacting a respective aldehyde with a sulfonium ylide.
Of preformed ylide was added and stirred for 2 days.
The active form of Tebbe 's reagent is often considered a titanium ylide.
About 3 equivalents of the ylide are employed in the described procedure.
This ylide can then attack pyruvate, which is held by the enzyme pyruvate decarboxylase.
The compound of formula XI may be obtained from the phosphorus ylide of formula,.
About 4 equivalents of the ylide methylene triphenylphosphorane were employed in this reaction.
No rinses with THF were done to maintain an approximately 1 M stock solution of the ylide.
Next, the solution of the ylide was added vía cannula to give a thick suspension.
EXAMPLES Ethylene oligomerization reactions were carried out using a sulfonated nickel ylide ( SUNY ) catalyst.
In the first step, a phosphorus ylide is prepared by treating a suitable phosphonium salt with a base.
Treatment with triphenylphosphine gives phosphonium salt 21-9, which is converted to the ylide with potassium hexamethyldisilazide.
The ylide IVd is then converted to tricarbonyl IVa by a two-step acylation / oxidation process.
The vast majority of reagents are monosubstituted at the ylide carbon either R1 or R2 as hydrogen.
Additional ylide solution was added until all of the 8CPTG was consumed.
Aluminium windows - Aluminum ylide - save energy.
The ylide ( I ) is then reacted with propionaldehyde under the standard conditions of the Wittig reaction.
The generation of the azomethine ylide 2 from 1a and 1b is straightforward.
The ylide 8 is reacted with an aldehyde to produce the alkene 9.
The aldehyde 3 is then reacted with the ylide of Formula,.
An appropriate organophosphorous ylide is contacted with an appropriate a-keto ester of structure ( 8 ).
Scheme IV illustrates an alternative preparation of the amino epoxide ( 5 ) utilizing a sulfur ylide.
The ylide may be prepared by reacting a corresponding alkyl halide with triphenylphosphine ( PPh3 ).
Which comprises, contacting a ketosulfoxonium ylide of Formula P-I,.
Of the supported ylide as prepared according to Example 1 is agitated in 20 ml of THF.
The first products, presumably formed irreversibly, are N2 and a carbonyl ylide.
The ylide formation is generally carried out at a temperature of from -78°C to ambient temperature.
An additional total of 0.14 mmol of ylide was added in this fashion.
