Examples of 'oxidative cleavage' in a sentence
Meaning of "oxidative cleavage"
oxidative cleavage: Refers to a chemical reaction involving the breaking of bonds through oxidation. This phrase is commonly used in organic chemistry and biochemistry contexts to describe specific reaction mechanisms
How to use "oxidative cleavage" in a sentence
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oxidative cleavage
The oxidative cleavage metabolite is pharmacologically inactive.
The mechanism of the oxidative cleavage is discussed.
Oxidative cleavage of the unsaturated nitrile.
Continuous process of oxidative cleavage of vegetable oils.
The oxidative cleavage reaction is a reaction that is well known.
The collagen can also be modified by oxidative cleavage.
Conveniently the oxidative cleavage is carried out in two steps.
These two acids are the easiest to analyze and characterize oxidative cleavage of the medium.
The oxidative cleavage step is carried out in the absence of organic solvent.
The Nap group was removed by oxidative cleavage with DDQ.
This oxidative cleavage is carried out using ammonium chlorochromate as oxidizing agent.
This example illustrates an alternative form of oxidative cleavage of the w-unsaturated nitrile.
Oxidative cleavage of olefins by ozonolysis, potassium permanganate, or potassium dichromate.
Similarly, polymers susceptible to oxidative cleavage are not stable in the disinfecting composition.
Oxidative cleavage of the alkenyl group under standard conditions e . g.
See also
White solid ; obtained from compound 3 by following the oxidative cleavage procedure.
Oxidative cleavage of the unsaturated nitrile or fatty acid ( as the case may be ).
The intermediate 67 may be accessed from an oxidative cleavage of the requisite olefin.
Thus, oxidative cleavage of the a-glycol occurred.
Preferably, this cyclization reaction is conducted by activation or oxidative cleavage of the olefin.
The oxidation and the oxidative cleavage can be combined in a work-up procedure.
Another mild procedure for the removal of the 5a-tocopheryl group is its oxidative cleavage.
More preferably, the oxidative cleavage reaction will produce an atiocyclosporin carboxaldehyde.
The final aldehyde intermediate 9 is then obtained vÃa oxidative cleavage of the phenylethenyl side chain.
Step 4c involves the oxidative cleavage of dihydroxy compound XXII to obtain the aldehyde XXIII.
Living organisms produce retinal ( RAL ) by irreversible oxidative cleavage of carotenoids.
In one embodiment, oxidative cleavage is performed using NaIO4.
For example, diols may be converted to aldehydes by oxidative cleavage e . g.
Optionally, the oxidation and the oxidative cleavage can be combined in a work-up procedure.
Oxidative cleavage reaction yields ( % moles of theoretical amount ).
Conversion to the aldehyde can be achieved by oxidative cleavage of the 2-phenylethenyl side chain.
Oxidative cleavage of the exocyclic olefin affords ketone VII-3.
The process as claimed in claim 1, wherein the oxidative cleavage is carried out by ozonolysis.
After alkylation, oxidative cleavage of the double bond provides the desired formula 51 aldehyde.
Hypochlorous acid inactivates leukotriene B4 by oxidative cleavage and / or halogenation.
This example illustrates the oxidative cleavage by reductive ozonolysis of the C 18 diacid resulting from example 2.
Alternative II, epoxidation by mCPBA in dichloromethane at decreased temp ., followed by oxidative cleavage.
In one embodiment, the oxidative cleavage is performed with NaIO4.
Oxidative cleavage of C-C bonds.
Compounds 102 are diols prepared by oxidative cleavage reactions followed by reduction.
Oxidative cleavage of the double bond in a compound of formula ( IX ) gives a diacid of formula ( X ).
Compound 17 is obtained by oxidative cleavage of the olefin of compound 16.
Keywords, synthesis, secoxyloganin, vinyl cuprate, oxidative cleavage.
Oxidative cleavage of the diol with NaIO4 produced aldehyde 24ah-ii.
The aldehyde 22 is obtained by the oxidative cleavage of the olefin group in compound 21.
Oxidative cleavage of the diol using lead tetraacetate in CH2Cl2 gives compound 32.
The aldehyde 17a is obtained by the oxidative cleavage of the olefin in 16a.
The vicinal diol moiety is liberated and oxidative cleavage yields the ( - ) - oleocanthal ( Formula Xa ).
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