Examples of 'reductive elimination' in a sentence
Meaning of "reductive elimination"
reductive elimination - Reductive elimination is a chemical reaction process in organometallic chemistry and catalysis where a metal center expels a ligand by breaking two covalent bonds simultaneously. This step is often involved in transition metal-catalyzed reactions and plays a key role in various chemical transformations, such as cross-coupling reactions and catalytic cycles
How to use "reductive elimination" in a sentence
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reductive elimination
Reductive elimination is the reverse of oxidative addition.
The complex can be decomposed readily by reductive elimination.
Reductive elimination liberates the tetrahydroanthracene compound.
The cycle is completed by the reductive elimination of the nitrile.
The oxidation mechanism ordinarily consists of a ligand exchange reaction followed by a reductive elimination.
These glycans are then released by reductive elimination and their mass analyzed.
The nature of the process suggests palladium insertion followed by hydride transfer and reductive elimination.
In a nondissociative mechanism reductive elimination occurs from the square planar complex itself.
As with oxidative addition, several mechanisms are possible with reductive elimination.
To a reductive elimination reaction to eliminate the elements of the groups X and Z.
These conditions avoid hydrogenolysis of double bonds or reductive elimination of halogens Org.
Reductive elimination gives ketone 3 with the regeneration of the active catalyst 9.
Selective desulfonylation may be carried out on β-hydroxy sulfones without reductive elimination.
Reductive elimination is a common step in organometallic reaction mechanisms, and particularly in catalytic cycles.
This intermediate can then rearrange to form a Y-shaped adduct, which can undergo faster reductive elimination.
See also
Reductive elimination is favored when the newly formed X-Y bond is strong.
On the key-role of SmI2 in the reductive elimination step.
It is also possible that reductive elimination occurs from a 3-coordinate intermediatelj formed by deprotonation of V.
Each in MeOH, only ( deprotected ) starting material is isolated without any reductive elimination.
Reductive elimination was found to be the limiting step for C-O and C-N bond formation.
Nitrotriol is also known to give the triol by reductive elimination ( path b ) Latour, et.
The second step is reductive elimination with formation of a new C-C bond and lead ( II ) acetate.
The reactions involve S-dealkylation followed by reductive elimination of R2S2.
Upon completion of the reductive elimination reaction, 214.5 mls acetic acid was added with stirring.
Potassium neopentoxide concentration dependence of the rate of reductive elimination of 4 in THF - d 8 at 47°C.
The rates for reductive elimination followed the following order, vinyl-vinyl > phenyl-phenyl > alkynyl-alkynyl > alkyl-alkyl.
Ar-Rh ( I ) regenerates by reductive elimination releasing methane.
Reductive elimination releases H2, which remains coordinated, giving complex 3.
Direct reductive elimination of Cu ( II ) to Cu ( 0 ) also takes place but is very slow.
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Examples of using Reductive
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Reductive elimination is the reverse of oxidative addition
It is notable for being capable of reductive dechlorination of chlorophenols
Reductive elimination liberates the tetrahydroanthracene compound
